Origin of sulphate in the unsaturated zone and groundwater of a loess aquifer     

Yin Long  Tianming Huang  Fen Zhang  Zhenbin Li  Baoqiang Ma  Yiman Li  Zhonghe Pang 《水文研究》2021,35(4):e14166

The use of the sulphate mass balance (SMB) between precipitation and soil water as a supplementary method to estimate the diffuse recharge rate assumes that the sulphate in soil water originated entirely from atmospheric deposition; however, the origin of sulphate in soil and groundwater is often unclear, especially in loess aquifers. This study analysed the sulphur (δ³⁴S-SO₄) and oxygen (δ¹⁸O-SO₄) isotopes of sulphate in precipitation, water-extractable soil water, and shallow groundwater samples and used these data along with hydrochemical data to determine the sources of sulphate in the thick unsaturated zone and groundwater of a loess aquifer. The results suggest that sulphate in groundwater mainly originated from old precipitation. When precipitation percolates through the unsaturated zone to recharge groundwater, sulphates were rarely dissolved due to the formation of CaCO₃ film on the surface of sulphate minerals. The water-extractable sulphate in the deep unsaturated zone (>10 m) was mainly derived from the dissolution of evaporite minerals and there was no oxidation of sulphide minerals during the extraction of soil water by elutriating soil samples with deionized water. The water-extractable concentration of SO₄ was not representative of the actual SO₄ concentration in mobile soil water. Therefore, the recharge rate cannot be estimated by the SMB method using the water-extractable concentration of SO₄ in the loess areas. This study is important for identifying sulphate sources and clarifying the proper method for estimating the recharge rate in loess aquifers.  相似文献   

南海北部西沙海槽沉积物管状黄铁矿特征及其形成机理^*          下载免费PDF全文

石思思  吴朝东  梁金强  王熠哲  叶云涛  方允鑫  马健  翟俪娜 《古地理学报》2020,22(1):175-192

南海北部西沙海槽S1站位的岩心柱沉积物中广泛发育自生矿物黄铁矿,其形态以管状为主,且具有内部中空的圈层结构。使用扫描电镜、电子探针、LA-ICP-MS、SIMS等测试方法研究了管状黄铁矿的形态及圈层结构,结果显示: (1)管状黄铁矿发育内部中空的圈层结构,其中内圈层(I_py)由莓球状黄铁矿呈五角十二面体紧密堆积组成,外圈层(O_py)由晶形较好晶粒较大的八面体黄铁矿组成,并混有沉积碎屑及钙质生物壳体;(2)内圈层和外圈层分别呈现出贫S富Fe和富S贫Fe的特征,其成因是甲烷渗漏造成的局部还原环境使得As进入黄铁矿中导致晶格空缺或被扭曲,从而促进Ni、Co、Cu、Zn、Pb等微量元素的掺入;(3)内圈层、外圈层发生了明显的硫同位素分馏现象,内圈层中 δ³⁴S 平均为-37.8‰,外圈层中 δ³⁴S 平均为-29.3‰。研究认为,管状黄铁矿作为曾经甲烷渗漏的通道,其生长机制可分为3个阶段: (1)气水通道形成阶段: 向上运移的甲烷流体在沉积物孔隙中逐渐形成气水通道;(2)外圈层形成阶段: 当向上运移的甲烷与硫酸盐发生甲烷厌氧氧化时,逐渐形成晶体较大、晶形较好的八面体黄铁矿外圈层;(3)内圈层形成阶段: 随着甲烷浓度逐渐降低,在气水通道中的微生物作用下,剩余甲烷与向下运移的硫酸盐继续反应形成莓球状黄铁矿内圈层。因此,南海北部的泥岩中大量发育的管状黄铁矿常常与地层中甲烷水合物的存在有关。  相似文献   

Geochemical evidence of ions’ sources and influences of meteorological factors on hydrochemistry of glacier snow meltwater in the source region of the Yangtze River     

Zong-Jie  Li  Jin-Zhu  Ma  Hai-Chao  Yu  Huan  Yang  Ling-Ling  Song  Zong-Xing  Li  Juan  Gui 《Environmental Earth Sciences》2020,79(10):1-17

The risk management of cascade reservoir systems (CRSs) is a major public challenge, and the establishment of risk criteria is critical to solving this iss  相似文献   

基于自然区块的城市热环境空间分异性研究     

杨智威  陈颖彪  吴志峰  千庆兰  黄清瑶 《地理科学进展》2019,38(12):1944-1956

通过有效解决建设用地子类划分,实现定量评价城市热环境的空间分异性,对改善城市生态环境、实现城市化的健康发展具有重要的意义和科学价值。论文以广州市为例,参考自然城市的概念,基于5类兴趣点(Point Of Interest,POI)开放数据,结合城市建设用地分类标准,构建5类自然区块;在Landsat 8遥感影像地表温度反演的基础上,计算分析自然区块下地表热场等级分布格局、热场平均值及热环境足迹范围,以对城市热环境空间分异性进行评价。研究表明：① 自然区块的构建,能准确地反映各类POI数据空间分布情况,能够实现对建设用地子类型的划分;② 5类自然区块内部地表热场等级均以高温像元为主,但等级分布具有显著差异。同时,自然区块的热场平均值由高到低的排序为：工业区块>商业服务业区块>交通与道路区块>居住区块>公共管理与服务区块;③ 自然区块形成的高温集聚区,存在热量扩散现象,实际影响范围大于其物理边界,5类自然区块的热环境足迹范围具有分异性。热环境足迹影响范围由大到小排序为：工业区块>商业服务业区块>居住区块>道路与交通区块>公共管理与服务区块。研究结果可为微观尺度上分析城市热环境、改善城市生态环境、实现城市化的健康发展提供科学依据。  相似文献   

Relative energy zero ratio-based approach for identifying pulse-like ground motions     

Liu  Ping  Li  Ning  Ma  Hua  Xie  Lili  Zhou  Baofeng 《地震工程与工程振动(英文版)》2020,19(1):1-16

Pulse-like ground motions are capable of inflicting significant damage to structures. Efficient classification of pulse-like ground motion is of great importance when performing the seismic assessment in near-fault regions. In this study, a new method for identifying the velocity pulses is proposed, based on different trends of two parameters: the short-time energy and the short-time zero crossing rate of a ground motion record. A new pulse indicator, the relative energy zero ratio(REZR), is defined to qualitatively identify pulse-like features. The threshold for pulse-like ground motions is derived and compared with two other identification methods through statistical analysis. The proposed procedure not only shows good accuracy and efficiency when identifying pulse-like ground motions but also exhibits good performance for classifying records with high-frequency noise and discontinuous pulses. The REZR method does not require a waveform formula to express and fit the potential velocity pulses; it is a purely signal-based classification method. Finally, the proposed procedure is used to evaluate the contribution of pulse-like motions to the total input energy of a seismic record, which dramatically increases the seismic damage potential.  相似文献   

马达加斯加石墨矿地质特征及其成因分析   总被引：1，自引：0，他引：1  

马金虎 《地质与勘探》2020,56(4):878-888

马达加斯加石墨矿资源丰富,找矿潜力大。对马达加斯加东部及西南部3个典型石墨矿床进行综合对比研究,发现其石墨矿成因类型为区域变质型,矿石工业类型以大鳞片晶质石墨为主,自然类型可分为片岩型、片麻岩型及变粒岩型,石墨矿赋矿地层为Graphite岩系。对含矿岩石进行主量元素分析,认为其原岩为富含有机质、富铝的砂质、粉砂质、泥质沉积碎屑岩;形成环境为活动大陆边缘区域和大陆岛弧区域。马达加斯加石墨矿床的形成均经历了多次变质作用,富含有机质岩石主要通过区域变质作用形成晶质石墨矿床,并在混合岩化及深层次韧性剪切作用下进一步富集成矿。  相似文献   

耦合土地利用回归与人口加权模型的PM2.5暴露风险评估     

邹雨轩  吴志峰  曹峥 《地球信息科学学报》2019,21(7):1018-1028

PM_2.5已成为人群健康的重要威胁之一,科学精准的暴露评估是PM_2.5风险防控的前提,为提升PM_2.5暴露精准评估,本文利用土地利用数据、道路数据、气象数据等构建PM_2.5土地利用回归反演模型,实现了2013年12月1日-2014年2月8日（冬季）广佛都市区PM_2.5时空动态演变监测,在此基础上将PM_2.5反演结果与人口密度数据耦合,分别从PM_2.5污染浓度与人口加权PM_2.5浓度2个方面,评估广佛都市区PM_2.5污染暴露风险。研究结果表明：① 土地利用回归模型能够较好的反映研究区域内PM_2.5的空间分布特征,R²大于0.78;② 2013年12月1日-2014年2月8日,广佛都市区PM_2.5浓度平均值呈现波动变化趋势,研究时段内,最高平均浓度为97.91 μg/m³ （12月29日-1月11日）,最低平均浓度为53.40 μg/m³ （1月26日-2月8日）,全时段PM_2.5浓度超WHO健康标准的面积占比达99.8%;③ 广佛都市区PM_2.5的空间分布具有异质性规律,其高值区分别位于广州市天河区、越秀区、番禺区北部、花都区北部及佛山市禅城区、南海区中部、三水区中部,低值区主要位于广州市白云区、番禺区东南部及佛山市顺德区南部。人口加权暴露风险存在2个高值中心,分别位于广州市和佛山市的主城区;④ 耦合人口加权模型前后,广佛都市区PM_2.5暴露风险高风险区空间分布发生变化,未考虑人口加权模型时,广佛深高值区较为分散,主要位于南海区、天河区、越秀区、禅城区,考虑人口加权模型后,高值区更加集中于广州市和佛山市的主城区。  相似文献   

张家口蔚县农村房屋抗震性能调查及统计分析     

马旭东  牛露  刘晓丹  刘龙  茅远哲  关恒瑜  刘贾贾  刘志辉 《震灾防御技术》2019,14(4):829-837

为进一步了解蔚县地区农村房屋的抗震性能，在该地区选取43个村庄、7732栋房屋进行实地调查和统计分析。主要调查房屋结构、建筑材料、房屋抗震构造措施等内容，分析各结构类型房屋抗震薄弱环节及房屋抗震性能，并统计分析经济、交通、地形等因素与房屋结构类型及抗震性能的关系，提出提高该地区农村房屋抗震性能的建议。  相似文献   

Jacobian matrix for near-infrared remote sensing based on vector radiative transfer model     

Bai  Wenguang  Zhang  Peng  Zhang  Wenjian  Li  Jun  Ma  Gang  Qi  Chengli  Liu  Hui 《中国科学:地球科学(英文版)》2020,63(9):1353-1365

Due to the polarization effects of the Earth's surface reflection and atmospheric particles' scattering, high-precision retrieval of atmospheric parameters from near-infrared satellite data requires accurate vector atmospheric radiative transfer simulations. This paper presents a near-infrared vector radiative transfer model based on the doubling and adding method. This new model utilizes approximate calculations of the atmospheric transmittance, reflection, and solar scattering radiance for a finitely thin atmospheric layer. To verify its accuracy, the results for four typical scenarios(single molecular layer with Rayleigh scattering, single aerosol layer scattering, multi-layer Rayleigh scattering, and true atmospheric with multi-layer molecular absorption, Rayleigh and aerosol scattering) were compared with benchmarks from a well-known model. The comparison revealed an excellent agreement between the results and the reference data, with accuracy within a few thousandths. Besides, to fulfill the retrieval algorithm, a numerical differentiation-based Jacobian calculation method is developed for the atmospheric and surface parameters. This is coupled with the adding and doubling process for the radiative transfer calculation. The Jacobian matrix produced by the new algorithm is evaluated by comparison with that from the perturbation method. The relative Jacobian matrix deviations between the two methods are within a few thousandths for carbon dioxide and less than 1.0×10~(-3)% for aerosol optical depth. The two methods are consistent for surface albedo, with a deviation below 2.03×10~(-4)%. All validation results suggest that the accuracy of the proposed radiative transfer model is suitable for inversion applications. This model exhibits the potential for simulating near-infrared measurements of greenhouse gas monitoring instruments.  相似文献   

Water Temperature Dynamics in a Complex of Reservoirs and Its Effect on the Temperature Patterns of a Mountain River     

Łukasz Wiejaczka  Małgorzata Kijowska-Strugała  Paweł Pierwoła  Mariusz Nowak 《Water Resources》2018,45(6):861-872

The article presents the spatial and temporal dynamics of water temperature in two reservoirs on the upper course of the Dunajec River in the Polish Carpathians. It aims at presenting how spatial patterns and time evolution of water temperature in the reservoirs affect the water temperature in the river. The analysis is based on the results of water temperature measurements in hydrometric verticals in two reservoirs as well as in the river upstream and downstream of the reservoirs. The measurements were carried out in 2012 and 2013, in hydrometeorological conditions typical for each season of the year. Based on the measurements, it has been demonstrated that the complex of reservoirs affects the water temperature in the river over the year and the existence of the smaller lower reservoir may attenuate the cooling or heating effect of the main reservoir on the river.  相似文献